000			03261cam a2200361 i 4500
001			17206105
003			EG-ScBUE
005			20250804094719.0
008			120312t2012 gw a f b 001 0 eng d
020			_a9783527327171 (pbk.)
020			_a3527327177 (pbk.)
040			_aUKM _beng _erda _cSTF _dCDX _dYDXCP _dBDX _dMUU _dSFU _dLMR _dKMS _dDLC _dBU-ScBUE
041	1		_aeng _hger
082	0	4	_a547.05045 _222 _bSTE
100	1		_aSteinborn, Dirk, _eauthor. _936214
245	1	0	_aFundamentals of organometallic catalysis / _cDirk Steinborn ; translated by Alan Frenkel.
264		1	_aWeinheim, Germany : _bWiley-VCH Verlag Gmbh & Co. KGaA, _c[2012]
264		4	_cc2012
300			_axvii, 456 pages : _billustrations ; _c24 cm
336			_2rdacontent _atext _btxt
337			_aunmediated _2rdamedia _bn
338			_avolume _bnc _2rdacarrier
504			_aIncludes bibliographical references and index.
505	0		_aPrinciples of organometallic catalysis-Elementary steps in organometallic catalysis-Hydrogenation of olefins-Hydroformylation of olefins and Fischer-Tropsch synthesis-Carbonylation of methanol and water-gas shift reaction-Metathesis-Oligomerization olefins-Polymerization of olefins-C-C linkage of dienes-C-C coupling reactions-Hydrocyanation, hydrosilylation, and hydroamination of olefins-Oxidation of olefins and alkanes-Nitrogen fixation.
520			_aCatalysis, the basic principle for overcoming the kinetic inhibition of chemical reactions, is fundamental in chemistry. In particular, organometallic catalysis plays an overwhelming role in both research and industry. It opens the way to entirely novel synthetic methods and finds widespread applications ranging from mass-production of every-day polymers to stereocontrolled synthesis of bioactive chemicals used as pharmaceuticals and agrochemicals. The targeted development of improved and novel catalysts demands understanding of the relationships between their structures and catalytic properties. Accordingly, this textbook offers the reader a fundamental understanding of the course of organometallic-catalyzed reactions, starting at the molecular level. The initial chapters explain the principles of catalysis and the elementary steps in organometallic catalysis. The book then explores important organometallic-catalyzed reactions, with a focus on mechanism. Current developments are emphasized throughout. Asymmetric synthesis is covered in depth. FInally, the book examines the catalytic behavior of particular metalloenzymes. A look at nitrogen fixation offers a comparative examination of the three major areas of catalysis--homogeneous, heterogeneous, and enzymatic. In addition to problems, the textbook offers solutions, making the book an invaluable learning tool. It is a must-have for advanced students in chemistry and biochemistry, as well as for inorganic and organic chemists, for those working with organometallics, and for those specializing in catalysis.
546			_aTranslated from the German.
650		7	_aCatalysis _vTextbooks. _2BUEsh _936215
650		7	_aOrganometallic chemistry _vTextbooks. _2BUEsh _936216
653			_bENGGEN _cOctober2014
655			_vReading book _934232
700	1		_aFrenkel, Alan, _etranslator. _936217
942			_2ddc _cBB
999			_c18455 _d18427